Enantio- and Diastereodifferentiating cis,trans-photoisomerization of 2β,3β-Diphenylcyclopropane-1aα-carboxylic acid derivatives in organized media

Cheung, Eugene ; Chong, Kenneth C. W. ; Jayaraman, Sivaguru ; Ramamurthy, V. ; Scheffer, John R. ; Trotter, James (2000) Enantio- and Diastereodifferentiating cis,trans-photoisomerization of 2β,3β-Diphenylcyclopropane-1aα-carboxylic acid derivatives in organized media Organic Letters, 2 (18). pp. 2801-2804. ISSN 1523-7060

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol0062190

Related URL: http://dx.doi.org/10.1021/ol0062190

Abstract

Four methods of asymmetric induction in the cis,trans-photoisomerization of 2β,3β-diphenylcyclopropane-1α-carboxylic acid derivatives were studied. Best results (ca. 80% de) were obtained by irradiation of chiral esters, amides, and salts in NaY and LiY zeolites and in the pure crystalline state.

Item Type:Article
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ID Code:55487
Deposited On:18 Aug 2011 11:43
Last Modified:18 Aug 2011 11:43

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