Sundaresan, Arun Kumar ; Ramamurthy, V. (2007) Making a difference on excited-state chemistry by controlling free space within a nanocapsule: photochemistry of 1-(4-alkylphenyl)-3-phenylpropan-2-ones Organic Letters, 9 (18). pp. 3575-3578. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol0713990
Related URL: http://dx.doi.org/10.1021/ol0713990
Abstract
The free space within a reaction cavity plays a determining role during the excited-state reaction of 1-(4-alkylphenyl)-3-phenylpropan-2-ones included within a capsule formed by two molecules of a deep cavity cavitand. By controlling the free space within the reaction cavity through remote alkyl substitution on the reactant ketone it is possible to control the yield of the rearrangement product shown above.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 55479 |
| Deposited On: | 18 Aug 2011 11:47 |
| Last Modified: | 18 Aug 2011 11:47 |
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