Controlling photochemistry with distinct hydrophobic nanoenvironments

Kaanumalle, Lakshmi S. ; Gibb, Corinne L. D. ; Gibb, Bruce C. ; Ramamurthy, V. (2004) Controlling photochemistry with distinct hydrophobic nanoenvironments Journal of the American Chemical Society, 126 (44). pp. 14366-14367. ISSN 0002-7863

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ja0450197

Related URL: http://dx.doi.org/10.1021/ja0450197

Abstract

A combination of hydrophobic forces and guest templation drive the assembly of cavitands into molecular capsules. Encapsulated guests such as dibenzyl ketones reside in an essentially dry environment, and upon irradiation, undergo rearrangement processes that are templated by the shape of the 1 nm × 2 nm cavity.

Item Type:Article
Source:Copyright of this article belongs to American Chemical Society.
ID Code:55470
Deposited On:18 Aug 2011 11:45
Last Modified:18 Aug 2011 11:45

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