Vishnumaya, ; Singh, Vinod K. (2007) Highly enantioselective water-compatible organocatalyst for Michael reaction of ketones to nitroolefins Organic Letters, 9 (6). pp. 1117-1119. ISSN 1523-7060
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Official URL: http://pubs.acs.org/doi/abs/10.1021/ol070082x
Related URL: http://dx.doi.org/10.1021/ol070082x
Abstract
A chiral diamine was found to catalyze enantioselective addition of ketones to nitroolefins in aqueous/saline/organic media. The products were obtained with excellent diastereoselectivities (syn/anti = 99:1) and enantioselectivities up to 99%. The reaction could be facilitated using a mild acid.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 55425 |
| Deposited On: | 18 Aug 2011 08:44 |
| Last Modified: | 18 Aug 2011 08:44 |
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