Vijaya Anand, R. ; Baktharaman, S. ; Singh, Vinod K. (2003) A ring-closing metathesis approach toward formal total synthesis of (+)-diplodialide A The Journal of Organic Chemistry, 68 (8). pp. 3356-3359. ISSN 0022-3263
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Official URL: http://pubs.acs.org/doi/abs/10.1021/jo034049%2B
Related URL: http://dx.doi.org/10.1021/jo034049+
Abstract
An asymmetric formal total synthesis of diplodialide A 1a has been achieved starting from methyl acetoacetate 6 and (R)-3-buten-2-ol 7. The macrocyclic ring core of (+)-diplodialide A 1a was constructed, in an excellent yield, by using a ring-closing metathesis strategy.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 55355 |
| Deposited On: | 18 Aug 2011 08:39 |
| Last Modified: | 18 Aug 2011 08:39 |
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