Saravanan, Parthasarathy ; Gupta, Suparna ; DattaGupta, Arpita ; Gupta, Sonia ; Singh, Vinod K. (1997) Reductive cleavage of tert-butyldimethylsilyl ether via intramolecular transfer of hydride Synthetic Communications, 27 (15). pp. 2695-2699. ISSN 0039-7911
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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...
Related URL: http://dx.doi.org/10.1080/00397919708004138
Abstract
The cleavage of α-hydroxy tert-butyldimethylsilyl ether to diol takes place efficiently with LAH. It has been proposed that the reaction proceeds via intramolecular hydride transfer from the alkoxy aluminium hydride. In order to substantiate this, reduction of TBDMS ether with LAH in a variety of substrates was studied.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Taylor and Francis Group. |
| ID Code: | 55272 |
| Deposited On: | 18 Aug 2011 08:32 |
| Last Modified: | 18 Aug 2011 08:32 |
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