DattaGupta, Arpita ; Singh, Ramsharan ; Singh, Vinod K. (1996) A mild and efficient method for the cleavage of tert-butyldimethylsilyl and tetrahydropyranyl ethers by ceric ammonium nitrate in methanol Synlett, 1996 (1). pp. 69-71. ISSN 0936-5214
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Official URL: https://www.thieme-connect.com/ejournals/abstract/...
Related URL: http://dx.doi.org/10.1055/s-1996-5320
Abstract
A variety of tert-butyldimethylsilyl (TBDMS) and tetrahydropyranyl (TFP) ethers were cleaved with ceric ammonium nitrate in methanol at 0 °C in short time. It has been shown that the reaction is chemoselective in a few cases. The primary TBDMS ethers have been cleaved selectively in the presence of THP ether and ketal.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Thieme Medical Publishers. |
| Keywords: | Deprotection; TBDMS Ether; THP Ether; CAN |
| ID Code: | 55253 |
| Deposited On: | 18 Aug 2011 08:30 |
| Last Modified: | 18 Aug 2011 08:30 |
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