A novel thermal Knoevenacel condensation via a thermal Michael reaction

Afzal, Jalees ; Vairamani, M. ; Hazra, B. C. ; Das, K. C. (2006) A novel thermal Knoevenacel condensation via a thermal Michael reaction Synthetic Communications, 10 (11). pp. 843-850. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397918008062767

Abstract

In connection with the total synthesis of natural products by retro-mass spectral approach, the thermal reaction between 6,7-dimethoxy-3-isochromanone 1 and benzalmalononitrile 3 was studied. The Knoevenagel condensation product was obtained over and above the expected Diels-Alder adduct. The scope, limitation and mechanism of the aforesaid unusual thermal Knoevenagel condensation through a thermal Michael reaction is described.

Item Type:Article
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ID Code:55198
Deposited On:18 Aug 2011 12:22
Last Modified:19 Aug 2011 04:35

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