Stacking of a benzenehexacarboxylic acid core in the crystal structure of benzenehexacarboxylic acid α-aminomethyl isobutyrate amide (MA-Aib6)-sodium nitrate complex

Ranganathan, Subramania ; Muraleedharan, K. M. ; Chandrashekhar Rao, C. H. ; Vairamani, M. ; Karle, Isabella L. ; Gilardi, Richard D. (2001) Stacking of a benzenehexacarboxylic acid core in the crystal structure of benzenehexacarboxylic acid α-aminomethyl isobutyrate amide (MA-Aib6)-sodium nitrate complex Chemical Communications (24). pp. 2544-2545. ISSN 1359-7345

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/2001...

Related URL: http://dx.doi.org/10.1039/B109465N

Abstract

MA-Aib6 forms discrete stacks with sandwiched water, sodium and nitrate ions, presenting a novel profile, where nine out of the 12 binding sites, of the six amides present, are involved in bonding with water, sodium and nitrate ions, with no inter-amide hydrogen bonding. This is the first example of the stacking of a benzenehexacarboxylic acid core.

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