Homochiral lithium amides: enantioselective deprotonation of cyclohexene oxide

Bhuniya, Debnath ; Singh, Vinod K. (1994) Homochiral lithium amides: enantioselective deprotonation of cyclohexene oxide Synthetic Communications, 24 (3). pp. 375-385. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0039791...

Related URL: http://dx.doi.org/10.1080/00397919408011196

Abstract

Reaction of cyclohexene oxide with chiral lithium amides has been studied and (S)-2-cyclohexen-1-ol was prepared in 20-82% ee. The optical purity was determined by proton NMR measurement of α-methoxy-α-(trifluoromethyl)phenylacetic acid (MTPA) derivative of the corresponding alcohol.

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Deposited On:18 Aug 2011 08:25
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