Occurrence of natural fullerenes in low grade metamorphosed proterozoic shungite from Karelia, Russia

Parthasarathy, G. ; Srinivasan, R. ; Vairamani, M. ; Ravikumar, K. ; Kunwar, A. C. (1998) Occurrence of natural fullerenes in low grade metamorphosed proterozoic shungite from Karelia, Russia Geochimica et Cosmochimica Acta, 62 (21-22). pp. 3541-3544. ISSN 0016-7037

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0016-7037(98)00242-7

Abstract

We report on the occurrence of fullerenes in Proterozoic shungite (˜2 Ga) from the shungite mine, Kondopoga, Karelia, Russia (62.12°N 34.17°E). The presence of fullerenes has been confirmed by mass spectrometry, with peaks at 360 and 720 amu (atomic mass unit), powder X-ray diffraction showing ten diffraction peaks corresponding to the fullerite structure with a = 1.4201(5) nm, and 13C nuclear magnetic resonance (NMR) spectroscopic studies, showing a peak at 143.2 ppm. In the Kondopoga shungite mine, fullerenes occur in silty shales that have experienced greenshist facies metamorphism.

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