Approaches to the synthesis of High-TC superconducting oxides in La-Ba-Cu-O and Y-Ba-Cu-O systems

Bhat, V. ; Ganguli, A. K. ; Nanjundaswamy, K. S. ; Mohan Ram, R. A. ; Gopalakrishnan, J. ; Rao, C. N. R. (1987) Approaches to the synthesis of High-TC superconducting oxides in La-Ba-Cu-O and Y-Ba-Cu-O systems Phase Transitions: A Multinational Journal, 10 (1-2). pp. 87-95. ISSN 0141-1594

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/0141159...

Related URL: http://dx.doi.org/10.1080/01411598708220084

Abstract

High-TC superconducting oxides of nominal La1.85Ba0.15 CuO4 and YBa2 Cu3 O7 have been prepared by using nitrate, carbonate, oxalate/malonate and citrate precursors. While the samples in the Y-system are generally monophasic YBa2Cu3O7-δ with TC around 90K, the preparations in the La-system are biphasic containing K2NiF4-like La1.85Ba0.15 CuO4 (TC=30K) and a perovskite-like phase with a much higher TC (200-300K). Effect of Ca, Zr, Ce as well as S substitution in YBa2Cu3O7-δ has also been investigated.

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