Covalent and noncovalent functionalisation and solubilisation of nanodiamond

Abstract

Covalent functionalisation of nanodiamond has been carried out by employing several methods. One of them involves the reaction of acid-treated nanodiamond with thionyl chloride followed by reaction with a long-chain aliphatic amine to produce the amide derivative. The second method involves reaction of acid-treated nanodiamond with an organosilicon or organotin reagent such as hexadecyltrimethoxysilane, dibutyldimethoxytin, and perfluoro-octyltriethoxysilane. The products of covalent functionalisation produce excellent dispersions in CCl₄ and toluene. SiO₂-and SnO₂-covered nanodiamond are obtained by heating the nanodiamond coated with the organosilane and the organotin reagents, respectively. By interaction of nanodiamond with surfactants such as sodium bis(2-ethylhexyl) sulphosuccinate (AOT), Triton X-100 (TX-100), polyvinyl alcohol (PVA), cetyltrimethylammonium bromide (CTAB), and tert-octylphenoxy poly(oxyethylene)ethanol (IGEPAL) gives good dispersions in water, the best dispersion with the lowest surfactant concentration being obtained with IGEPAL.