Singh, Chandan ; Singh, Joginder ; Sukh Dev, (1977) Higher isoprenoids-VII: A new approach to the degradation of cyclolaudenol side-chain Tetrahedron, 33 (14). pp. 1759-1763. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/0...
Related URL: http://dx.doi.org/10.1016/0040-4020(77)84056-8
Abstract
An efficient new procedure for the degradation of cyclolaudenyl acetate to 3 β - acetoxy - 4,4,14α -trimethyl - 9, 19 - cyclo - 5α - pregnan - 20 - one and/or 3 β - acetoxy - 4,4,14 α- trimethyl - 9,19 - cyclo - 5 α -androstan - 17 - one is described. The key-step is simultaneous base-catalysed dehydrohalogenation and isomerisation of the resulting olefin, of a suitably derived halide.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 54482 |
| Deposited On: | 11 Aug 2011 14:32 |
| Last Modified: | 11 Aug 2011 14:32 |
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