Photorearrangement of aryl esters in micellar medium

Singh, Anil K. ; Sonar, Sanjay M. (1985) Photorearrangement of aryl esters in micellar medium Synthetic Communications, 15 (12). pp. 1113-1121. ISSN 0039-7911

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Effect of a micelle (SDS) on the photorearrangement of aryl esters have been investigated. Thus, phenyl, p- and m-cresyl, and 2-naphthyl benzoates yielded the corresponding o-hydroxybenzophenones as a major product in high yield. Phenyl cinnamate gave 2-hydroxychalcone. 2,4,6-Tri-butylphenylbenzoate, however, underwent decarboxylation yielding 2,4,6-tri-t-butyl biphenyl in quantitative yield.

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