Singh, Anil K. ; Khade, Prashant K. (2005) Anthracene-9-methanol- a novel fluorescent phototrigger for biomolecular caging Tetrahedron Letters, 46 (33). pp. 5563-5566. ISSN 0040-4039
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.06.026
Abstract
Photoexcitation of a solution of anthracene-9-methanol derived esters at ~386 nm in CH3CN/H2O (3:2 v/v) results in fluorescence emission in the 380-480 nm range, with quantum yields of fluorescence (φf) in the 0.01-0.09 range and releases of the carboxylic acids in good chemical yields (43-100%), with quantum yields of photoreaction (φPR, i.e., the photodisappearance of the esters) in the 0.067-0.426 range.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Caging; Anthracene-9-methanol; Esters; Photochemistry; Phototrigger |
| ID Code: | 54098 |
| Deposited On: | 11 Aug 2011 11:47 |
| Last Modified: | 11 Aug 2011 11:47 |
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