Organic reactions in a solid matrix-II: Alumina-induced oxirane rearrangements

Joshi, V. S. ; Damodaran, N. P. ; Sukh Dev, (1971) Organic reactions in a solid matrix-II: Alumina-induced oxirane rearrangements Tetrahedron, 27 (2). pp. 459-474. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4020(01)90716-1

Abstract

Rearrangement of oxiranes, on contact with active Al2O3, earlier studied with methyldialkyl-substituted 1,2-epoxides, has now been extended to 1,2-dialkyl epoxides (cyclohexene oxide, cycloheptene oxide) and β-himachalene monoepoxide (tetrasubstituted). Isomerisation of citronellol epoxide has been investigated to detect any participation of the OH function in oxirane opening. To gauge the importance of topology of the substrate rearrangement of 3β,4β-epoxycarane has been studied and the results compared with those obtained earlier with 3α,4α-epoxycarane.

Item Type:Article
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ID Code:53947
Deposited On:10 Aug 2011 14:32
Last Modified:10 Aug 2011 14:32

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