Joshi, V. S. ; Damodaran, N. P. ; Sukh Dev, (1968) Organic reactions in a solid matrix-I: Alumina-induced oxirane rearrangements Tetrahedron, 24 (17). pp. 5817-5830. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)96312-4
Abstract
A fairly generation transformation of methyldialkyl-substituted 1,2-epoxides to the corresponding vinylidene, allylic secondary alcohols, on contact with active Al2O3, is described. A systematic study of some of the reaction variables of this transformation has also been carried out. The epoxides thus studied include those derived from the following olefins: 1-methylcyclopentene, 1-methylcyclohexene, 1-methylcycloheptene, α-pinene and Δ3-carene.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 53943 |
| Deposited On: | 10 Aug 2011 09:00 |
| Last Modified: | 10 Aug 2011 09:00 |
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