Tetrathia- and tetraoxarubyrins: aromatic, core-modified, expanded porphyrins

Srinivasan, Alagar ; Reddy, VenkatRam M. ; Jeyaprakash Narayanan, S. ; Sridevi, Bashyam ; Pushpan, Simi K. ; Ravikumar, Murugaeson ; Chandrashekar, Tavarekere K. (1997) Tetrathia- and tetraoxarubyrins: aromatic, core-modified, expanded porphyrins Angewandte Chemie International Edition, 36 (23). pp. 2598-2601. ISSN 1433-7851

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/anie.19...

Related URL: http://dx.doi.org/10.1002/anie.199725981

Abstract

The remarkably simple synthesis of tetrathia- and tetraoxarubyrins 1 and 2 is achieved by the routes presented here. Spectroscopic, 1H NMR, and electrochemical data suggest that 1, 2, and their protonated derivatives are aromatic 26 π electron systems, and the protonated derivatives form stable complexes in solution with anions such as F-, N3-, and adenosine 5'-monophosphate.

Item Type:Article
Source:Copyright of this article belongs to John Wiley and Sons, Inc.
Keywords:Bithiophenes; Porphyrinoids; Rubyrin; Sensitizers
ID Code:5328
Deposited On:18 Oct 2010 08:43
Last Modified:27 May 2011 11:47

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