Effect of cyclodextrine cavity size on twisted intramolecular charge transfer emission: dimethylamino benzonitrile in β -cyclodextrine

Nag, Ashis ; Dutta, Rina ; Chattopadhyay, Nitin ; Bhattacharyya, Kankan (1989) Effect of cyclodextrine cavity size on twisted intramolecular charge transfer emission: dimethylamino benzonitrile in β -cyclodextrine Chemical Physics Letters, 157 (1-2). pp. 83-86. ISSN 0009-2614

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Official URL: http://dx.doi.org//10.1016/0009-2614(89)87212-4

Related URL: http://dx.doi.org/10.1016/0009-2614(89)87212-4

Abstract

Emission spectra of p-N,N-dimethylamino benzonitrile (DMABN) in aqueous β -cyclodextrine (β -CD) solutions are reported. In β -CD two distinct kinds of emission are observed, one with enhanced nonpolar emission (at 355 nm) and the other exhibiting enhanced TICT emission (at 480 nm). The former is attributed to those DMABN molecules which are totally inside the β -CD cavity while the latter is due to DMABN molecules only partially enclosed in the cavity.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:5309
Deposited On:18 Oct 2010 08:35
Last Modified:07 Feb 2011 07:39

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