Adiabaticity in electrochemical electron transfer: a perspective from a diffusion-reaction equation approach

Sebastian, K. L. ; Chakravarti, Nalini (1993) Adiabaticity in electrochemical electron transfer: a perspective from a diffusion-reaction equation approach Journal of Electroanalytical Chemistry, 351 (1-2). pp. 57-63. ISSN 0022-0728

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0022-0728(93)80223-5

Abstract

A theoretical study of electrochemical electron transfer (ECET) using the diffusion-reaction equation approach is presented. The rate expression for the transfer of an electron from an ion in solution to the metal electrode is derived. The concept of adiabaticity as applied to ECET is looked into in the light of this approach.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:52983
Deposited On:04 Aug 2011 12:14
Last Modified:04 Aug 2011 12:14

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