Synthesis, structure, and reactivity of the nickel(II) complex of 7-aza-1,4-dithiacyclononane

McAuley, A. ; Subramanian, S. (1990) Synthesis, structure, and reactivity of the nickel(II) complex of 7-aza-1,4-dithiacyclononane Inorganic Chemistry, 29 (15). pp. 2830-2837. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic00340a022

Related URL: http://dx.doi.org/10.1021/ic00340a022

Abstract

The "missing" member of the series of ligands, based on cyclononane [9]aneNxSy (x+y=3), namely 7-aza-1,4-dithiacyclononane, L3, [9]aneNS2, has been synthesized and characterized. A key step in the synthesis is the final detosylation, upon which comments are made. The Ni(II) complex has been prepared as a perchlorate salt and investigated by X-ay diffraction. Octahedral symmetry is observed, with each nitrogen in an axial position. The species [Ni(L3)2](ClO4)2 crystallizes in the monoclinic space group P21/a.

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