EPR and structural investigations on single crystals of potassium niobium peroxide fluoride hydrate, K2NbO2F5·H2O

Geetha, Ramakrishnan ; Rao, Pillutla Sambasiva ; Babu, Varghese ; Subramanian, Sankaran (1991) EPR and structural investigations on single crystals of potassium niobium peroxide fluoride hydrate, K2NbO2F5·H2O Inorganic Chemistry, 30 (7). pp. 1630-1635. ISSN 0020-1669

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Official URL: http://pubs.acs.org/doi/abs/10.1021/ic00007a039

Related URL: http://dx.doi.org/10.1021/ic00007a039

Abstract

The single-crystal structural investigation of dipotassium pentafluoroperoxoniobate hydrate, K2NbO2F5.H2O (DPPN), is reported. The crystals are monoclinic with space group C2, and the unit cell dimensions are a=8.927 (4) Å, b=8.926 (3) Å, c=9.266 (2) Å, β=99.93 (1)°, and Z=4. The least-squares refinement of positional and anisotropic thermal parameters for all non-hydrogen atoms led to an R factor of 0.057.

Item Type:Article
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ID Code:51947
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