Jeyaprakash Narayanan, Seenichamy ; Sridevi, Bashyam ; Chandrashekar, Tavarekere K. ; Englich, Ulrich ; Ruhlandt-Senge, Karin (1999) Core-modified smaragdyrins: first examples of stable meso-substituted expanded corrole Organic Letters, 1 (4). pp. 587-590. ISSN 1523-7060
Full text not available from this repository.
Official URL: http://pubs.acs.org/doi/abs/10.1021/ol990108n
Related URL: http://dx.doi.org/10.1021/ol990108n
Abstract
A synthetic access to the first members of expanded corroles 1 and 2 is achieved through formation of two direct pyrrole-pyrrole links by an oxidative coupling reaction. Spectroscopic and structural analysis reveal that 1 and 2 are 22Π aromatic macrocycles despite the nonplanar structure and properties resemble that of isocorroles rather than 22Π sapphyrins.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to American Chemical Society. |
| ID Code: | 5185 |
| Deposited On: | 18 Oct 2010 06:37 |
| Last Modified: | 27 May 2011 11:41 |
Repository Staff Only: item control page
