Dasgupta, Arnab ; Sivaram, Swaminathan (1994) Synthesis and polymerization of N-trimethylsilylacrylamide: a hydrophobic acrylamide Macromolecular Chemistry and Physics, 195 (10). pp. 3361-3368. ISSN 1022-1352
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/macp.19...
Related URL: http://dx.doi.org/10.1002/macp.1994.021951007
Abstract
N-Trimethylsilylacrylamide (TMSAm), a hydrophobic acrylamide, has been synthesized and characterized. The monomer could be polymerized in benzene by 2,2'-azoisobutyronitrile or benzoyl peroxide to poly(TMSAm). The silylated polymer was characterized with 1H NMR. Poly(TMSAm) is stable in the absence of moisture. It could be quantitatively hydrolyzed to polyacrylamide under mild conditions. The monomer has been copolymerized with styrene in benzene by benzoyl peroxide to yield polymers which on hydrolysis give copolymers of acrylamide and styrene.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 51646 |
| Deposited On: | 29 Jul 2011 03:59 |
| Last Modified: | 29 Jul 2011 03:59 |
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