Sen Sarma, Soumen ; Sivaram, Swaminathan (1997) Magnesium chloride supported bis(cyclopentadienyl)titanium(IV) dichloride-MAO catalyst for ethylene polymerization Macromolecular Chemistry and Physics, 198 (2). pp. 495-503. ISSN 1022-1352
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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/macp.19...
Related URL: http://dx.doi.org/10.1002/macp.1997.021980222
Abstract
A novel magnesium chloride supported titanocene catalyst was synthesized using a soluble tetrahydrofuran complex of magnesium chloride. The suported catalyst polymerized ethylene with high activities in presence of methylaluminoxane. The significant feature of the supported metallocene catalyst is that it shows high polymerization activity at low Al/Ti ratio and at higher temperatures compared to soluble catalyst. The role of support in stabilizing the active species on the metallocene is discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to John Wiley and Sons. |
| ID Code: | 51632 |
| Deposited On: | 29 Jul 2011 03:59 |
| Last Modified: | 29 Jul 2011 03:59 |
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