A radical cyclisation route to 3-alkyl furans. Synthesis of perillene and dendrolasin

Srikrishna, Adusumilli ; Sunderbabu, Gajendran (1988) A radical cyclisation route to 3-alkyl furans. Synthesis of perillene and dendrolasin Chemistry Letters, 17 (2). pp. 371-372. ISSN 0366-7022

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Official URL: http://www.journalarchive.jst.go.jp/english/jnlabs...

Related URL: http://dx.doi.org/10.1246/cl.1988.371

Abstract

A general three step synthesis of 3-alkyl furans, including Perillene and Dendrolasin, from alk-2-ynyl alcohols is described via̲ radical cyclisation of 2-bromo-1-ethoxyethyl alk-2-ynyl ethers to 2-ethoxy-4-alkylidene tetrahydrofurans.

Item Type:Article
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