X-ray K-absorption studies of some ruthenium compounds

Bhide, V. G. ; Kaicker, S. K. (1974) X-ray K-absorption studies of some ruthenium compounds Journal of Physics and Chemistry of Solids, 35 (6). pp. 695-698. ISSN 0022-3697

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00223...

Related URL: http://dx.doi.org/10.1016/S0022-3697(74)80225-8


X-ray K-absorption studies of ruthenium in ruthenium metal,RuO2, K2(RuCl6) and K 4[Ru(CN)6]: 3H2O have been carried out using 400 mm bent crystal (mica) spectrograph. K-absorption edge of ruthenium in these compounds lies on the higher energy side with respect to that in the ruthenium metal; the divalentK4[Ru(CN)6].3H2O gives the shift in the range of tetravalent compounds RuO2 and K2[RuCl6]. This discrepancy has been explained on the basis of molecular orbital picture.

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