Critical phenomena in the coexistence curve of the binary liquid system

Lele, M. V. ; Subramanyam, S. V. ; Gopal, E. S. R. (1971) Critical phenomena in the coexistence curve of the binary liquid system Chemical Physics Letters, 11 (4). pp. 542-544. ISSN 0009-2614

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Official URL: http://www.sciencedirect.com/science/article/pii/0...

Related URL: http://dx.doi.org/10.1016/0009-2614(71)80406-2

Abstract

The coexistence curve of the carbondisulphide-acetic anhydride system has been measured. The shape of the curve in the critical region (Xc≈70.89 mole % mole % CS2 and Tc≈30.56°C) is determined by the equation |X'-X''|=Bx (1-T/Tc)β with the critical indices β=0.34±0.01 and Bx=1.7±0.1 over a range 10−6 < (Tc-T)/Tc < 10−2. The values of β and Bx agree with those of other systems and the theoretical predictions of the Ising model.

Item Type:Article
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ID Code:51514
Deposited On:28 Jul 2011 14:37
Last Modified:06 Jul 2012 05:01

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