Studies on the preparation and characterization of bis-dithiocarbamato derivatives of di-n-butyl- and di-n-hexyl Sn(IV)

Sharma, C. P. ; Kumar, N. ; Khandpal, M. C. ; Chandra, S. ; Bhide, V. G. (1981) Studies on the preparation and characterization of bis-dithiocarbamato derivatives of di-n-butyl- and di-n-hexyl Sn(IV) Journal of Inorganic and Nuclear Chemistry, 43 (5). pp. 923-930. ISSN 0022-1902

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/002219...

Related URL: http://dx.doi.org/10.1016/0022-1902(81)80151-0

Abstract

Di-alkyl tin(IV) bis-dithiocarbamato complexes of the type R2Sn(IV)[R'R"dtc]2 or R2Sn(IV)[morph. dtc]2 (where R = n-Bu, n-Hex, R' = R" = Me, Et, i-Pr; R'= Me and R" = Ph) have been prepared by the reaction of di-n-butyl or di-n-hexyl Sn(IV) dichloride with the sodium salt of respective dithiocarbamic acid in 1:2 molar ratio in dry acetone. The IR, 1H NMR and Mossbauer studies indicate an anisobidentate character for the dtc (dithiocarbamate) ligand in these complexes.

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