Polymorphism of rubidium nitrate

Salhotra, P. P. ; Subbarao, E. C. ; Venkateswarlu, P. (1968) Polymorphism of rubidium nitrate Physica Status Solidi B, 29 (2). pp. 859-864. ISSN 0370-1972

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Official URL: http://onlinelibrary.wiley.com/doi/10.1002/pssb.19...

Related URL: http://dx.doi.org/10.1002/pssb.19680290238


Rubidium nitrate exists in four polymorphic forms in the solid state, three of which (IV, III, and I) have been well characterized. Data are presented, from dilatometric and X-ray studies, to confirm a rhombohedral symmetry for phase II rather than the tetragonal, suggested by Brown and McLaren (1962). The mechanism of structural changes, at the III → II → I phase transitions, is described.

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