Concomitant desulfurization and transesterification of alkyl thionocarbamates

Joshi, Uday M. ; Patkar, Laxmikant N. ; Rajappa, Srinivasachari (2004) Concomitant desulfurization and transesterification of alkyl thionocarbamates Synthetic Communications, 34 (1). pp. 33-39. ISSN 0039-7911

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Official URL: http://www.tandfonline.com/doi/abs/10.1081/SCC-120...

Related URL: http://dx.doi.org/10.1081/SCC-120027235

Abstract

Alkyl carbamate (such as 1) reacts with triphosgene at the nitrogen atom, whereas the analogous thionocarbamates (5) react at the sulfur. Subsequent treatment with various phenols or alcohols leads to the corresponding aryl carbamates or alkyl carbamates (6) respectively. The process thus involves both desulfurization and transesterification.

Item Type:Article
Source:Copyright of this article belongs to Taylor and Francis Group.
Keywords:Alkyl Carbamate; Aryl Carbamate; Thionocarbamate; Sulfur
ID Code:50340
Deposited On:23 Jul 2011 07:20
Last Modified:23 Jul 2011 07:20

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