Nitroketene-s, n-acetals as precursors for nitroacetamides and the elusive nitrothioacetahides

Manjunatha, Sulur G. ; Venodhar Reddy, K. ; Rajappa, Srinivasachari (1990) Nitroketene-s, n-acetals as precursors for nitroacetamides and the elusive nitrothioacetahides Tetrahedron Letters, 31 (9). pp. 1327-1330. ISSN 0040-4039

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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...

Related URL: http://dx.doi.org/10.1016/S0040-4039(00)88798-5

Abstract

1-Amino-1-methylthio-2-nitroethenes (2) can be converted in high yields to the Nitroacetamides (3) by Hg2+ catalysed hydrolysis and to the Nitrothioacetamides (4) by Na2S in ethanol-acetic acid.

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