Tandel, Sagun K. ; Rajappa, Srinivasachari ; Pansare, Sunil V. (1993) Conversion of thiocarbamates to carbamates Tetrahedron, 49 (34). pp. 7479-7486. ISSN 0040-4020
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Official URL: http://linkinghub.elsevier.com/retrieve/pii/S00404...
Related URL: http://dx.doi.org/10.1016/S0040-4020(01)87224-0
Abstract
Treatment of methyl N-methylthionocarbamate (2a) with a catalytic amount of iodine or conc. H2SO4 results in the unexpected formation of the isomer, methyl N-methylthiolcarbamate (3a) in 90% yield. This has subsequently been transformed into methyl N-methylcarbamate (4a), by sodium methoxide. A curious transformation of methyl N-methyldithiocarbamate (1a) to (4a) on prolonged treatment with sodium methoxide is also discussed.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| ID Code: | 50333 |
| Deposited On: | 23 Jul 2011 07:19 |
| Last Modified: | 23 Jul 2011 07:19 |
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