Rajappa, Srinivasachari ; Nair, Mohan D. ; Advani, Bhagwan G. ; Sreenivasan, Ramaswami ; Desai, Jagdish A. (1979) A general synthesis of thiazoles. Part 3. Comparative evaluation of different functionalised thioureas as precursors Journal of the Chemical Society, Perkin Transactions 1 . pp. 1762-1764. ISSN 0300-922X
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Official URL: http://pubs.rsc.org/en/content/articlelanding/1979...
Related URL: http://dx.doi.org/10.1039/P19790001762
Abstract
N-Acyl-N'-monosubstituted thioureas (9) react with phenacyl bromide to produce thiazolines (10) and not thiazoles (4), as claimed. The addition products of N-arylbenzamidines and phenyl isothiocyanate react with phenacyl bromide to give 2-anilino-5-benzoyl-4-phenylthiazole (4a). The adduct (11) of methyl benzimidate and phenyl isothiocyanate yields thiazoles (4a) and (12) by reaction with phenacyl bromide and bromonitromethane, respectively.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Royal Society of Chemistry. |
| ID Code: | 50321 |
| Deposited On: | 23 Jul 2011 07:17 |
| Last Modified: | 23 Jul 2011 07:17 |
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