Conversion of carbonimidodithioates to carbamates

Anbazhagan, Mariappan ; Indrasena Reddy, T. ; Rajappa, Srinivasachari (1997) Conversion of carbonimidodithioates to carbamates Journal of the Chemical Society, Perkin Transactions 1 (11). pp. 1623-1628. ISSN 0300-922X

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Carbonimidodithioates derived from primary amines or α-amino acid esters have been converted to N-benzyloxycarbonyl derivatives under mild conditions by treatment first with sodium benzyl alcoholate and then with water. N-Benzyloxycarbonyl α-amino acids have been generated from the methyl esters by alkaline hydrolysis or from the allyl esters by Pd0-catalysed de-allylation.

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Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:50316
Deposited On:23 Jul 2011 06:37
Last Modified:18 May 2016 04:40

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