Raman study of stoichiometric and Zn-doped Fe3O4

Gupta, Rajeev ; Sood, A. K. ; Metcalf, P. ; Honig, J. M. (2002) Raman study of stoichiometric and Zn-doped Fe3O4 Physical Review B: Condensed Matter and Materials Physics, 65 (10). 104430_1-104430_8. ISSN 1098-0121

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Official URL: http://prb.aps.org/abstract/PRB/v65/i10/e104430

Related URL: http://dx.doi.org/10.1103/PhysRevB.65.104430

Abstract

We report here our Raman studies on Fe3-xZnxO4(x=0,0.015,0.03) across the Verwey transition in the temperature range 20-300 K. The changes in Raman spectra as a function of doping show that the changes are gradual for samples with higher Zn doping. Allen's formula has been used to estimate the strength of electron-phonon interaction from the observed lineshape parameters. These estimates show that there is strong electron-phonon coupling in this system and is highest for the T2g3 mode in comparison to A1g and T2g2 modes.

Item Type:Article
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ID Code:50249
Deposited On:22 Jul 2011 13:52
Last Modified:22 Jul 2011 13:52

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