Gelation of aqueous pectin solutions: a dynamic light scattering study

Narayanan, Janaky ; Deotare, Vinod W. ; Bandyopadhyay, Ranjini ; Sood, A. K. (2002) Gelation of aqueous pectin solutions: a dynamic light scattering study Journal of Colloid and Interface Science, 245 (2). pp. 267-273. ISSN 0021-9797

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1006/jcis.2001.8055

Abstract

We report the dynamic light scattering study of the gelation of aqueous solutions of the biopolymer, pectin, induced by the addition of calcium chloride. The time correlation function data are analyzed under the framework of the coupling model. As the solution enters the semidilute regime where gelation sets in, the relaxation process shows a stretched exponential behavior. The stretching exponent decreases and the characteristic time of the stretched exponential diverges as the system evolves to a gel. Aqueous pectin solutions in the presence of 0.1 M NaCl show similar behavior. Thus, the molecular relaxation modes of pectin solutions can be well described by the coupling model.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:50194
Deposited On:22 Jul 2011 13:52
Last Modified:22 Jul 2011 13:52

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