Ragunathan, Kaliappa G. ; Bharadwaj, Parimal K. (1993) Template synthesis of a macrobicyclic cryptand having mixed donors via [2+3] Schiff base condensation Proceedings of the Indian Academy of Sciences - Chemical Sciences, 105 (3). pp. 215-217. ISSN 0253-4134
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Official URL: http://www.ias.ac.in/j_archive/chemsci/105/4/215-2...
Related URL: http://dx.doi.org/10.1007/BF02877485
Abstract
Tris(2-aminoethyl)amine undergoes [2+3] Schiff base condensation with diisobutyraldehyde disulphide in presence of Cs+ ion as the template. This Schiff base, on subsequent reduction by NaBH4, affords the cryptand (3) in overall 52% yield.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Indian Academy of Sciences. |
| Keywords: | Macrobicyclic Cryptand; Template Synthesis; Transition Metal Cryptates |
| ID Code: | 4950 |
| Deposited On: | 18 Oct 2010 06:10 |
| Last Modified: | 16 May 2016 15:31 |
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