Evidence of electron exchange between Fe2+ and Fe3+ ions on tetrahedral and octahedral sites in Fe2MoO4

Gupta, M. P. ; Sinha, A. P. B. ; Kanetkar, S. M. ; Date, S. K. ; Nigavekar, A. S. (1979) Evidence of electron exchange between Fe2+ and Fe3+ ions on tetrahedral and octahedral sites in Fe2MoO4 Journal of Physics C: Solid State Physics, 12 (12). p. 2401. ISSN 0022-3719

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Official URL: http://iopscience.iop.org/0022-3719/12/12/025

Related URL: http://dx.doi.org/10.1088/0022-3719/12/12/025

Abstract

Enriched Fe2MoO4 spinel was studied by Mossbauer spectroscopy in the temperature interval of 77-732K. The electrical conductivity measurements were carried out in the temperature range 298-475K. From these studies, it was concluded that fast electron exchange takes place amongst Fe3+ and Fe2+ ions situated at A as well as at B sites in the spinel lattice. The transition temperature TN=350K was determined by the temperature scanning method.

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