Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol

Srikrishna, Adusumilli ; Vijaykumar, Dange (1997) Stereocontrolled synthesis of (±)-α-pinguisene and (±)-pinguisenol Journal of the Chemical Society, Perkin Transactions 1 (22). pp. 3295-3296. ISSN 0300-922X

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Total synthesis of (±)-α-pinguisene 1 and (±)-pinguisenol 2, employing an orthoester Claisen rearrangement and an intramolecular diazo ketone cyclopropanation reaction for the stereospecific construction of vicinal quaternary carbon atoms, is described.

Item Type:Article
Source:Copyright of this article belongs to Royal Society of Chemistry.
ID Code:48887
Deposited On:19 Jul 2011 08:41
Last Modified:19 Jul 2011 08:41

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