A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of β-microbiotene, microbiotol and cyclocuparanol

Srikrishna, A. ; Anitha Nagamani, S. (1999) A short and efficient regioselective approach to the C-6 to C-19 segment of bifurcaranes and a formal total synthesis of β-microbiotene, microbiotol and cyclocuparanol Journal of the Chemical Society, Perkin Transactions 1 (23). pp. 3393-3394. ISSN 0300-922X

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Official URL: http://pubs.rsc.org/en/Content/ArticleLanding/1999...

Related URL: http://dx.doi.org/10.1039/A908033C

Abstract

Employing an epoxide rearrangement based ring contraction reaction, a short and efficient regioselective approach to the C-6 to C-19 segment of the toluquinol substituted diterpenes bifurcaranes, and its extension to a formal total synthesis of the sesquiterpenes (±)-β-microbiotene, (±)-microbiotol and (±)-cyclocuparanol are described.

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