A regioselective total synthesis of the fungal sesquiterpene (±)-lagopodin A

Srikrishna, A. ; Ramesh Babu, R. ; Ravikumar, P. C. (2007) A regioselective total synthesis of the fungal sesquiterpene (±)-lagopodin A Synlett (4). 0655-0657. ISSN 0936-5214

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Official URL: http://www.thieme-connect.com/ejournals/abstract/s...

Related URL: http://dx.doi.org/10.1055/s-2007-967971

Abstract

A highly regiocontrolled total synthesis of fungal ­sesquiterpene lagopodin A, employing a combination of Claisen rearrangement-intramolecular diazoketone cyclopropanation and a highly regioselective cyclopropane ring cleavage, is described.

Item Type:Article
Source:Copyright of this article belongs to Thieme Medical Publishers.
Keywords:Natural Products; Total Synthesis; Rearrangement; Ring Closure; Ring Cleavage
ID Code:48814
Deposited On:15 Jul 2011 12:32
Last Modified:15 Jul 2011 12:32

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