Enantiospecific first total synthesis of (+)-2β-hydroxysolanascone, the aglycone of the phytoalexin isolated from flue-cured tobacco leaves

Srikrishna, A. ; Ramasastry, S. S. V. (2006) Enantiospecific first total synthesis of (+)-2β-hydroxysolanascone, the aglycone of the phytoalexin isolated from flue-cured tobacco leaves Tetrahedron Letters, 47 (3). pp. 335-339. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.11.014

Abstract

The first total synthesis of (+)-2β-hydroxysolanascone, the aglycone of the phytoalexin 2β-hydroxysolanascone-β-glucopyranoside isolated from flue-cured tobacco leaves (N. tabacum L., OCL), and its 2,10-diepi- and 2α-epimers has been accomplished, starting from the readily available monoterpene (R)-carvone.

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