Enantiospecific synthesis of tricyclo[5.2.1.04,8]decanes via acid catalysed rearrangement of isotwistanes

Srikrishna, A. ; Satyanarayana, G. ; Ravi Kumar, P. (2006) Enantiospecific synthesis of tricyclo[5.2.1.04,8]decanes via acid catalysed rearrangement of isotwistanes Tetrahedron Letters, 47 (3). pp. 363-366. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2005.11.008

Abstract

An acid catalysed rearrangement was employed for the enantiospecific conversion of isotwistanol to tricyclo[5.2.1.04,8]decanes, which provided support for the proposed biosynthesis of allopupukeananes from pupukeananes. The strategy has been further extended to the enantiospecific synthesis of a homobrexane.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Molecular Rearrangement; Isotwistanes; Pupukeananes; Allopupukeanane
ID Code:48780
Deposited On:15 Jul 2011 11:47
Last Modified:15 Jul 2011 11:47

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