First enantiospecific synthesis of (−)-9-pupukeanone

Srikrishna, A. ; Ravi Kumar, P. (2002) First enantiospecific synthesis of (−)-9-pupukeanone Tetrahedron Letters, 43 (6). pp. 1109-1111. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(01)02336-X

Abstract

The first enantiospecific total synthesis of (−)-9-pupukeanone, starting from (R)-carvone employing a combination of Michael-Michael reaction and an intramolecular rhodium carbenoid C---H insertion reaction as key steps, is described.

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ID Code:48777
Deposited On:15 Jul 2011 11:41
Last Modified:15 Jul 2011 11:41

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