Stereospecific construction of three contiguous quaternary carbon atoms. Synthesis of (±)-3-methoxythaps-8-ene

Srikrishna, A. ; Ramachary, D. B. (2002) Stereospecific construction of three contiguous quaternary carbon atoms. Synthesis of (±)-3-methoxythaps-8-ene Tetrahedron Letters, 43 (15). pp. 2765-2768. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/S0040-4039(02)00381-7

Abstract

Synthesis of (±)-3-methoxythapsene via stereospecific construction of three contiguous quaternary carbon atoms, employing a combination of a Claisen rearrangement and an intramolecular diazoketone cyclopropanation as key reactions, is described.

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ID Code:48769
Deposited On:15 Jul 2011 11:41
Last Modified:15 Jul 2011 11:41

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