Carbanion cyclisation of esters. Part 2: enantiospecific construction of the tricyclic framework of the marine sesquiterpenes, spirodysins'

Srikrishna, A. ; Ravi Kumar, P. ; Ramasastry, S. S. V. (2004) Carbanion cyclisation of esters. Part 2: enantiospecific construction of the tricyclic framework of the marine sesquiterpenes, spirodysins' Tetrahedron Letters, 45 (2). pp. 383-386. ISSN 0040-4039

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tetlet.2003.10.165

Abstract

Enantiospecific construction of the bicyclo[4.3.0]nonan-8-one 17 employing a lithium and liquid ammonia mediated carbanion cyclisation of the δ-methyl-δ,ε-unsaturated ester 13, and its elaboration to the tricyclic framework of the marine sesquiterpenes spirodysins are described.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
ID Code:48760
Deposited On:15 Jul 2011 11:45
Last Modified:15 Jul 2011 11:45

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