The first total synthesis of (±)-laurokamurene B

Srikrishna, A. ; Khan, I. A. ; Ramesh Babu, R. ; Sajjanshetty, A. (2007) The first total synthesis of (±)-laurokamurene B Tetrahedron, 63 (51). pp. 12616-12620. ISSN 0040-4020

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Official URL: http://www.sciencedirect.com/science/article/pii/S...

Related URL: http://dx.doi.org/10.1016/j.tet.2007.10.021

Abstract

The first total synthesis of the rearranged aromatic sesquiterpene (±)-laurokamurene B, isolated from the Chinese red alga Laurencia okamurai Yamada, has been accomplished, confirming the structure of the natural product. A combination of Ireland-Claisen rearrangement and ring-closing metathesis was employed as key reactions.

Item Type:Article
Source:Copyright of this article belongs to Elsevier Science.
Keywords:Laurenes; Cuparenes; Laurokamurenes A and B; Ring-closing Metathesis; Ireland-Claisen Rearrangement
ID Code:48759
Deposited On:15 Jul 2011 11:50
Last Modified:15 Jul 2011 11:50

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