Srikrishna, A. ; Satyanarayana, G. (2005) A formal total synthesis of (±)-9-isocyanoneopupukeanane Tetrahedron, 61 (37). pp. 8855-8859. ISSN 0040-4020
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Official URL: http://www.sciencedirect.com/science/article/pii/S...
Related URL: http://dx.doi.org/10.1016/j.tet.2005.07.016
Abstract
A formal total synthesis of the marine sesquiterpene (±)-9-isocyanoneopupukeanane starting from the readily available monoterpene carvone has been accomplished employing a combination of intermolecular Michael addition-intramolecular Michael addition reaction and an intramolecular rhodium carbenoid C-H insertion reaction as key steps, and identifying the isopropenyl group as a masked hydroxy group.
| Item Type: | Article |
|---|---|
| Source: | Copyright of this article belongs to Elsevier Science. |
| Keywords: | Marine Sesquiterpenes; Neopupukeanane; Double Michael Reaction; Rhodium CH Insertion Reaction |
| ID Code: | 48746 |
| Deposited On: | 15 Jul 2011 10:21 |
| Last Modified: | 15 Jul 2011 10:21 |
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